Journal article
Uranium-hydrogen interactions: synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium(III)
Chemical communications (Cambridge, England), Vol.46(3), pp.407-408
01/21/2010
DOI: 10.1039/b919490h
PMID: 20066307
Abstract
The reaction of UCl(4) with Na(H(3)BNMe(2)BH(3)) in diethyl ether affords the uranium(III) product U(H(3)BNMe(2)BH(3))(3), which has been crystallized in two different structural isomers depending on the crystallization solvent. Both forms are polymeric, but the nature of the bridging interaction is different in the two forms.
Details
- Title: Subtitle
- Uranium-hydrogen interactions: synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium(III)
- Creators
- Scott R Daly - School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, IL 61801, USAGregory S Girolami
- Resource Type
- Journal article
- Publication Details
- Chemical communications (Cambridge, England), Vol.46(3), pp.407-408
- DOI
- 10.1039/b919490h
- PMID
- 20066307
- NLM abbreviation
- Chem Commun (Camb)
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Publisher
- Royal Society of Chemistry; England
- Language
- English
- Date published
- 01/21/2010
- Academic Unit
- Chemistry
- Record Identifier
- 9983985831802771
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