Journal article
rac-cis, cis-Dicarbonyldichlorido{1-[2(diphenylphosphanyl)benzyl]-3-mesitylimidazol- 2-ylidene} ruthenium(II) dichloromethane monosolvate
Acta crystallographica. Section E, Crystallographic communications, Vol.68(8), pp.M1121-m1121
08/01/2012
DOI: 10.1107/S1600536812032515
PMCID: PMC3414164
PMID: 22904771
Abstract
The Ru-II atom in the title compound, [RuCl2(C31H29N2P)(CO)(2)]center dot CH2Cl2, exhibits a distorted octahedral coordination environment. The bond angles of the cis substituents at the Ru II atom range from 82.72 (9) to 97.20 (3)degrees. This molecule is of interest in the field of catalytic transfer hydrogenation.
Details
- Title: Subtitle
- rac-cis, cis-Dicarbonyldichlorido{1-[2(diphenylphosphanyl)benzyl]-3-mesitylimidazol- 2-ylidene} ruthenium(II) dichloromethane monosolvate
- Creators
- Gregory J. Domski - Augustana CollegeSallie A. Hohenboken - Augustana CollegeDale C. Swenson - University of Iowa
- Resource Type
- Journal article
- Publication Details
- Acta crystallographica. Section E, Crystallographic communications, Vol.68(8), pp.M1121-m1121
- Publisher
- Int Union Crystallography
- DOI
- 10.1107/S1600536812032515
- PMID
- 22904771
- PMCID
- PMC3414164
- ISSN
- 2056-9890
- eISSN
- 2056-9890
- Number of pages
- 10
- Grant note
- Augustana College
- Language
- English
- Date published
- 08/01/2012
- Academic Unit
- Chemistry
- Record Identifier
- 9984622745902771
Metrics
4 Record Views