Magnetic materials and metallic particles and methods of making same

New magnetic materials and new metallic particles, new methods of making and using same, for example, to prepare magnetically modified electrodes and fuel cells, and coated metallic particles in general. The present invention discloses methods of preparation of cheaper and more uniformly sized magnetic and metallic microparticles formed from the exemplary materials magnetite, nickel, samarium cobalt and neodymium iron boron. In addition, the present invention discloses methodology for preparation and use of coated magnetic and metallic microparticles, in particular, exemplary siloxyl coating of magnetic particles, metallic particles, and magnetic and metallic microparticles with an exemplary silane, 3-aminopropyltrimethoxysilane, that is cross linked thereon. In addition, methods and results are described for preparing and using larger siloxyl coated samarium cobalt milliparticles. Coated magnetic milliparticles and magnetic microparticles are useful as component of composites that are applied to electrodes to alter electrochemical fluxes across those electrodes, as well as to alter chemical reactions on surfaces of those electrodes, when magnetically susceptible reactions occur there.