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Suppression of charge-density wave and superconductivity in a lithiated NbSe$_2$ monolayer
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Suppression of charge-density wave and superconductivity in a lithiated NbSe$_2$ monolayer

Hari Paudyal and Michael E Flatté
ArXiV.org
Cornell University
07/16/2025
DOI: 10.48550/arxiv.2507.11856
url
https://doi.org/10.48550/arxiv.2507.11856View
Preprint (Author's original)This preprint has not been evaluated by subject experts through peer review. Preprints may undergo extensive changes and/or become peer-reviewed journal articles. Open Access

Abstract

We present an \textit{ab initio} investigation of the long-range charge density wave (CDW) order and superconducting properties of the pristine and lithiated NbSe$_2$ monolayer. Stable CDW structures are obtained through atomic reconstruction driven by soft-mode distortions and lithiation, respectively, lead to significant electronic modifications that suppress the CDW order. This suppression is attributed to anisotropic atomic distortions, along with a reduction in the electronic density of states at the Fermi level. As a result, the electron--phonon coupling strength is suppressed, particularly in the lithiated structure, due to reduced contributions from low-frequency phonons, primarily associated with in-plane Nb vibrations. Finally, we observe a sizable anisotropy in the superconducting gap on the Fermi surface, with a superconducting transition temperature of approximately 8~K in the distorted, and 4~K in the lithiated, CDW NbSe$_2$ monolayer.
Physics - Superconductivity

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