Journal article
A solid-state [2 + 2] photodimerization involving coordination of Ag(I) ions to 2-pyridyl groups
Journal of coordination chemistry, Vol.71(16-18), pp.2875-2883
09/17/2018
DOI: 10.1080/00958972.2018.1501480
Abstract
Photoreactive Ag(I) complexes of p-toluenesulfonate ions with the unsymmetrical alkene trans-1-(4-acetoxyphenyl)-2-(2-pyridyl)ethylene 1 is reported. The crystal [Ag(p-tol)(1)2]•(H2O) (p-tol = p-toluenesulfonate) undergoes a [2 + 2] photocycloaddition reaction in quantitative yield to afford the head-to-tail (ht) photoproduct rctt-1,3-bis(2-pyridyl)-2,4-bis(4-acetoxyphenyl)cyclobutane 2 regioselectively. The aromatic rings of the olefin participate in face-to-face π–π interactions and adopt an anti-conformation to position the carbon–carbon double bonds (C = C) in a suitable orientation to undergo photoreaction between neighboring complexes.
Details
- Title: Subtitle
- A solid-state [2 + 2] photodimerization involving coordination of Ag(I) ions to 2-pyridyl groups
- Creators
- Gonzalo Campillo-Alvarado - Department of Chemistry, University of IowaKaterina Aslan - Department of Biological Sciences, Webster UniversityMichael A Sinnwell - Department of Chemistry, University of IowaEric W Reinheimer - Department of Chemistry and the W.M. Keck Foundation Center for Molecular Structure, California State UniversityS. V. Santhana Mariappan - Department of Chemistry, University of IowaLeonard R MacGillivray - Department of Chemistry, University of IowaRyan H Groeneman - Department of Biological Sciences, Webster University
- Resource Type
- Journal article
- Publication Details
- Journal of coordination chemistry, Vol.71(16-18), pp.2875-2883
- DOI
- 10.1080/00958972.2018.1501480
- ISSN
- 0095-8972
- eISSN
- 1029-0389
- Publisher
- Taylor & Francis
- Grant note
- CONACYT-COVEICYDET University of Iowa DMR-1708673 / National Science Foundation
- Language
- English
- Date published
- 09/17/2018
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216588502771
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