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Supporting Information. A solid-state [2 + 2] photodimerization involving coordination of Ag(I) ions to 2-pyridyl groups
Taylor & Francis
01/01/2023
DOI: 10.6084/m9.figshare.6876119.v3
Abstract
Photoreactive Ag(I) complexes of p-toluenesulfonate ions with the unsymmetrical alkene trans-1-(4-acetoxyphenyl)-2-(2-pyridyl)ethylene 1 is reported. The crystal [Ag(p-tol)(1)2]•(H2O) (p-tol = p-toluenesulfonate) undergoes a [2 + 2] photocycloaddition reaction in quantitative yield to afford the head-to-tail (ht) photoproduct rctt-1,3-bis(2-pyridyl)-2,4-bis(4-acetoxyphenyl)cyclobutane 2 regioselectively. The aromatic rings of the olefin participate in face-to-face π-π interactions and adopt an anti-conformation to position the carbon-carbon double bonds (C = C) in a suitable orientation to undergo photoreaction between neighboring complexes.
Details
- Title: Subtitle
- Supporting Information. A solid-state [2 + 2] photodimerization involving coordination of Ag(I) ions to 2-pyridyl groups
- Creators
- Gonzalo Campillo-AlvaradoKaterina AslanMichael A. SinnwellEric W. ReinheimerS. V. Santhana MariappanLeonard R. MacGillivrayRyan H. Groeneman
- Resource Type
- Other
- Publisher
- Taylor & Francis
- DOI
- 10.6084/m9.figshare.6876119.v3
- Language
- English
- Date published
- 01/01/2023
- Academic Unit
- Chemistry; Pharmaceutical Sciences and Experimental Therapeutics
- Record Identifier
- 9984528122302771
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